Bonding

bonding:  any joining together of atoms or molecules

chemical bond or intramolecular bond:  a strong bond between atoms or individual ions, resulting from the sharing or transfer of electrons

intermolecular bond:  a weak bond between molecules or ions, which holds the molecules of a liquid or solid together.  (We will study these in more detail later in the course.)

ion:  an atom or group of atoms that has a charge, because it has either gained or lost electrons.

polyatomic ion:  a group of atoms that are bonded to each other that behave chemically like a single ion.  A polyatomic ion always has a specific formula and a specific charge.

   For example:  the sulfate ion has the chemical formula SO42−.  It is made of one sulfur atom and 4 oxygen atoms.  Chemically, it behaves like a single atom with a −2 charge.


Types of Chemical Bonds

ionic bond:  when a positive ion and a negative ion are held together by the electrical attraction of their charges.

·      ionic bonds occur between a metal and a non-metal.

·      the positive ion (cation) is always either the ion of a metal or a positive polyatomic ion.

·      the negative ion (anion) is always either the ion of a nonmetal or a negative polyatomic ion.

·      the difference between the electronegativity of the nonmetal and the electronegativity of the metal (Δχ) is usually ≥ 1.7

covalent bond:  when two atoms form a bond by sharing (“co-“) their valence (“-valent”) electrons.

·      covalent bonds occur only between non-metals

·      the electronegativity difference (Δχ) between the two nonmetals is usually 1.7

metallic bond:  when atoms in a metal form a network of positive ions and loosely held electrons.

·      metallic bonds, as the name suggests, occur only between metals

·      metallic bonds are often described as a “sea of electrons” because the valence electrons are free to move from one atom to another.  This is how metals conduct electricity.