When Can A Reaction Happen?

In class, you saw some demonstrations.  The first one was the following reaction between aluminum metal and copper (II) chloride:

              Al (s) + CuCl2 (aq) AlCl3 (aq) + Cu (s)          (1)

The reverse reaction (the same reaction in the opposite direction) is:

              Cu (s) + AlCl3 (aq) CuCl2 (aq) + Al (s)          (2)

However, this didn’t happen in the demo.  Reaction (1) proceeded until all of the aluminum metal and CuCl2 were used up, and there was only AlCl3 and copper metal in the beaker.  Once that happened, the beaker was set for reaction (2), but reaction (2) didn’t happen.


The second demo was the reaction between sodium carbonate (Na2CO3) and calcium chloride (CaCl2):

  Na2CO3 (aq) + CaCl2 (aq) NaCl (aq) + CaCO3 (ppt)    (3)

However, once the calcium carbonate is formed, it doesn’t redissolve.  I.e., reaction (3) happens, but the reverse reaction (4), doesn’t:

   CaCO3 (s) + NaCl (aq) CaCl2 (aq) + Na2CO3 (aq)     (4)

 

Why might reactions (1) and (3) happen, but not reactions (2) and (4)?